Reduction of sulfoxides catalyzed by the commercially available manganese complex MnBr(CO)<sub>5</sub>-Reference-Cited by-同舟云学术

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Reduction of sulfoxides catalyzed by the commercially available manganese complex MnBr(CO)₅

Published:2024 Issue:18 Volume:22 Page:3746-3751
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Lourenço Daniel L.¹,Fernandes Ana C.¹^ORCID

Affiliation:

1. Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

Abstract

The commercially available, inexpensive and air-stable manganese catalyst MnBr(CO)5 has proven to be an excellent catalyst for the reduction of a wide variety of sulfoxides to the corresponding sulfides in excellent yields and good chemoselectivity.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00204K

Reference65 articles.

1. Selective Deoxygenation of Sulfoxides to Sulfides with Phosphites Catalyzed by Dichlorodioxomolybdenum(VI)

2. A novel method for the reduction of sulfoxides and pyridine N-oxides with the system silane/MoO2Cl2

3. Reduction of sulfoxides with boranes catalyzed by MoO2Cl2

4. Efficient recyclable catalytic system for deoxygenation of sulfoxides: catalysis of ionic liquid-molybdenum complexes in ionic liquid solution

5. Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics

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