Reactivity of NHC/diphosphene-coordinated Au(i)-hydride-Reference-Cited by-同舟云学术

Reactivity of NHC/diphosphene-coordinated Au(i)-hydride

Published:2021 Issue:6 Volume:57 Page:809-812
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dhara Debabrata¹²³^ORCID,Scheschkewitz David⁴⁵⁶⁷^ORCID,Chandrasekhar Vadapalli¹²³⁸⁹^ORCID,Yildiz Cem B.¹⁰¹¹¹²¹³^ORCID,Jana Anukul¹²³^ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad, Gopanpally

2. Hyderabad-500046

3. India

4. Krupp-Chair of General and Inorganic Chemistry

5. Saarland University

6. 66123 Saarbrücken

7. Germany

8. Department of Chemistry

9. Indian Institute of Technology Kanpur

10. Department of Medicinal and Aromatic Plants

11. University of Aksaray

12. Aksaray

13. Turkey

Abstract

We report the reactivity of NHC/diphosphene-stabilized Au(i)-hydride towards substrates with C–C and N–N multiple bonds. It reveals NHC/diphosphene-Au(i)-hydride is more reactive than NHC-Au(i)-hydride and also the reactivity pattern is different.

Funder

Department of Atomic Energy, Government of India

Science and Engineering Research Board

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC05461E

Reference52 articles.

1. Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

2. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications

3. Surface Chemistry-Mediated Near-Infrared Emission of Small Coinage Metal Nanoparticles

4. Synthesis of Coinage-Metal Nanoparticles from Mesityl Precursors

5. Ultrastable Gold Nanoparticles Modified by Bidentate N-Heterocyclic Carbene Ligands

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