Redox behavior of potassium doped and transition metal co-doped Ce0.75Zr0.25O2 for thermochemical H2O/CO2 splitting

Author:

Portarapillo Maria1,Landi Gianluca2ORCID,Luciani Giuseppina1ORCID,Imparato Claudio1,Vitiello Giuseppe13ORCID,Deorsola Fabio A.4ORCID,Aronne Antonio1ORCID,Di Benedetto Almerinda1

Affiliation:

1. Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Univ. of Naples Federico II, P.le Tecchio 80, 80125, Naples, Italy

2. Institute of Sciences and Technologies for Sustainable Energy and Mobility, CNR, P.le Tecchio 80, 80125, Naples, Italy

3. CSGI, Center for Colloids and Surface Science, 50019, Sesto Fiorentino (FI), Italy

4. Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy

Abstract

Potassium doped and co-doped ceria–zirconia show improved CO2/H2O splitting activity. This holds huge promise for the design of high performance systems for solar thermochemical splitting cycles allowing the production of solar fuels.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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