Affiliation:
1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe 76131, Germany
Abstract
The first half-sandwich complexes of the cyclononatetraenyl are reported. Coordination and deccordination of THF leads to the formation of either the ionic [LnIII(η3-BH4)2(thf)5][Cnt] or the polymeric compound [LaIII(η9-Cnt)(η3-BH4)2(thf)].
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis