PhI(OAc)2-mediated 1,2-aminohalogenation of alkynes: a general access to (E)-4-(halomethylene)oxazolidin-2-ones-Reference-Cited by-同舟云学术

PhI(OAc)2-mediated 1,2-aminohalogenation of alkynes: a general access to (E)-4-(halomethylene)oxazolidin-2-ones

Published:2017 Issue:18 Volume:15 Page:3964-3967
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang RuiJia¹²³⁴,Zou Huaxu¹²³⁴,Xiong Yi¹²³⁴,Yi Niannian¹²³⁴,Deng Wei¹²³⁴,Xiang Jiannan¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics

2. Hunan University

3. Changsha 410082

4. China

Abstract

A new PhI(OAc)₂-mediated 1,2-aminohalogenation of prop-2-yn-1-yl carbamates and halogen sources is presented with excellent selectivity. The reaction is general for the construction of (E)-4-(halomethylene)oxazolidin-2-ones through the three-membered ring or N-radical.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00509A

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