1-Bromoethene-1-sulfonyl fluoride (1-Br-ESF), a new SuFEx clickable reagent, and its application for regioselective construction of 5-sulfonylfluoro isoxazoles-Reference-Cited by-同舟云学术

1-Bromoethene-1-sulfonyl fluoride (1-Br-ESF), a new SuFEx clickable reagent, and its application for regioselective construction of 5-sulfonylfluoro isoxazoles

Published:2018 Issue:35 Volume:54 Page:4477-4480
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Leng Jing¹²³⁴⁵,Qin Hua-Li¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry

2. Chemical Engineering and Life Science

3. and State Key Laboratory of Silicate Materials for Architectures Wuhan University of Technology

4. Wuhan

5. P. R. China

Abstract

A unique SuFEx clickable tris-electrophile, 1-Br-ESF, was developed and applied for the synthesis of 5-sulfonylfluoro isoxazoles with exclusive regioselectivity.

Funder

National Natural Science Foundation of China

Wuhan University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC00986D

Reference42 articles.

1. Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry

2. Selective and Orthogonal Post-Polymerization Modification using Sulfur(VI) Fluoride Exchange (SuFEx) and Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) Reactions

3. A Heck-Matsuda Process for the Synthesis of β-Arylethenesulfonyl Fluorides: Selectively Addressable Bis-electrophiles for SuFEx Click Chemistry

4. Palladium-Catalyzed Fluorosulfonylvinylation of Organic Iodides

5. A Synthesis of “Dual Warhead” β-Aryl Ethenesulfonyl Fluorides and One-Pot Reaction to β-Sultams

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