A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor–acceptor interactions

Author:

Mochida Tomoyuki1234,Funasako Yusuke12345,Takahashi Kazuyuki1234,Inokuchi Makoto5678,Sakurai Takahiro9310,Ikeda Shohei112310,Ohta Hitoshi12310,Mori Hatsumi131415,Uruichi Mikio1617

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kobe University

4. Rokkodai, Nada, Japan

5. Department of Applied Chemistry

6. Faculty of Engineering

7. Tokyo University of Science

8. Yamaguchi, Onoda, Japan

9. Center for Supports to Research and Education Activities

10. Kobe, Japan

11. Department of Physics

12. Molecular Photoscience Research Center

13. Institute for Solid State Physics

14. The University of Tokyo

15. Kashiwa, Japan

16. Institute for Molecular Science

17. Okazaki, Japan

Abstract

[Dineopentyl-biferrocene]2[Cl1TCNQ]7, which has a high donor–acceptor ratio of 2 : 7, contains a linear paramagnetic hexamer of Cl1TCNQ.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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