Spectroscopic evidence for selenium(iv) dimerization in aqueous solution-Reference-Cited by-同舟云学术

Spectroscopic evidence for selenium(iv) dimerization in aqueous solution

Published:2015 Issue:22 Volume:44 Page:10508-10515
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kretzschmar J.¹²³⁴,Jordan N.¹²³⁴,Brendler E.⁵⁶⁷⁴,Tsushima S.¹²³⁴^ORCID,Franzen C.¹²³⁴,Foerstendorf H.¹²³⁴,Stockmann M.¹²³⁴,Heim K.¹²³⁴,Brendler V.¹²³⁴

Affiliation:

1. Helmholtz-Zentrum Dresden-Rossendorf

2. Institute of Resource Ecology

3. 01328 Dresden

4. Germany

5. Institute of Analytical Chemistry

6. Technical University Bergakademie Freiberg

7. 09599 Freiberg

Abstract

MP2 predicted IR spectra of different aqueous Se(iv) species revealed features characteristic of the hydrogen selenite dimer, (HSeO₃)₂²⁻. IR experiments, supported by⁷⁷Se NMR spectra, evidenced the existence of this dimeric species.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00730E

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