An iron(ii) spin-crossover metallacycle from a back-to-back bis-[dipyrazolylpyridine]
Author:
Affiliation:
1. School of Chemistry
2. University of Leeds
3. Leeds
4. UK LS2 9JT
5. Department of Chemical and Biological Sciences
6. University of Huddersfield
7. Huddersfield
8. UK HD1 3DH
Abstract
Iron(ii) and zinc(ii) complexes of bis[2,6-di(pyrazol-1-yl)pyrid-4-yl]disulfide assemble into tetranuclear metallacycles according to ES-MS, DOSY NMR and conductivity data. The iron complex exhibits a thermal spin-state equilibrium in solution, which the iron centres appear to undergo independently of each other.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00732A
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1. A proficient multivariate approach for iron(ii) spin crossover behaviour modelling in the solid state;Dalton Transactions;2023
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3. Quantitative Assessment of Ligand Substituent Effects on σ‐ and π‐Contributions to Fe−N Bonds in Spin Crossover Fe II Complexes;Chemistry – A European Journal;2022-03-21
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