Host–guest complexation of ionic liquid with α- and β-cyclodextrins: a comparative study by 1H-NMR, 13C-NMR and COSY-Reference-Cited by-同舟云学术

Host–guest complexation of ionic liquid with α- and β-cyclodextrins: a comparative study by 1H-NMR, 13C-NMR and COSY

Published:2018 Issue:17 Volume:42 Page:14542-14550
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Banjare Manoj Kumar¹²³⁴^ORCID,Behera Kamalakanta⁵⁶⁴,Satnami Manmohan L.¹²³⁴,Pandey Siddharth⁷⁸⁴,Ghosh Kallol K.¹²³⁴^ORCID

Affiliation:

1. School of Studies in Chemistry

2. Pt. Ravishankar Shukla University

3. Raipur (C.G.)

4. India

5. Centre for Interdisciplinary Research in Basic Sciences

6. JMI

7. Department of Chemistry

8. Indian Institute of Technology Delhi

Abstract

The inclusion complexation of 1-butyl-3-methylimidazolium octylsulphate [Bmim][OS] with host α- and β-cyclodextrins (CDs) has been explored by ¹H NMR, ¹³C NMR and COSY methods. The insertion of a guest molecule into the cavity of CD is clearly reflected by changes in ¹H-NMR and ¹³C-NMR chemical shift values and COSY NMR suggest that both H-bonding and electrostatic interactions involved to the complexation.

Funder

University Grants Commission

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01840E

Reference45 articles.

1. Supramolecular Chemistry at Interfaces: Host–Guest Interactions for Fabricating Multifunctional Biointerfaces