Dy2NiRuO6 perovskite with high activity and durability for the oxygen evolution reaction in acidic electrolyte

Author:

Rodríguez-García Isabel1ORCID,Gómez de la Fuente José Luis1,Galyamin Dmitry1ORCID,Tolosana-Moranchel Álvaro1,Kayser Paula23ORCID,Salam Mohamed Abdel4ORCID,Alonso José Antonio2ORCID,Calle-Vallejo Federico56,Rojas Sergio1ORCID,Retuerto María1ORCID

Affiliation:

1. Grupo de Energía y Química Sostenibles, Instituto de Catálisis y Petroleoquímica, CSIC, C/Marie Curie 2, 28049, Madrid, Spain

2. Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Inés de la Cruz 3, 28049 Madrid, Spain

3. Dep. Q. Inorgánica I, Facultad Químicas, Universidad Complutense, Avda. Complutense s/n, 28040-Ciudad Universitaria, Madrid, Spain

4. Chemistry Department, Faculty of Science, King Abdulaziz University, P. O Box 80200, Jeddah, 21589, Saudi Arabia

5. Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF), Department of Advanced Materials and Polymers: Physics, Chemistry and Technology, University of the Basque Country UPV/EHU, Avenida Tolosa 72, 20018 San Sebastián, Spain

6. IKERBASQUE, Basque Foundation for Science, Plaza de Euskadi 5, 48009 Bilbao, Spain

Abstract

This work reports a family of Ru-based perovskites for acid OER. Dy2NiRuO6 displays the highest activity and stability for more than 400 OER cycles. Its high activity is related to short Ru–O bonds and to a surface local ratio of Ni : Ru close to 1 : 1.

Funder

King Abdulaziz University

Consejería de Educación, Juventud y Deporte, Comunidad de Madrid

Ministerio de Ciencia e Innovación

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

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