Significant differences in photophysical and photovoltaic properties of flexible chain terminated homoleptic tris-Ir(iii) complexes

Author:

You Duoquan1,Yang Tianjian1,Zhou Aihua1,Li Siyuan2,Lv Kaiqi1,Ma Huili1ORCID,Zhong Hongliang2ORCID,Tao Youtian1ORCID

Affiliation:

1. Key Lab for Flexible Electronics and Institute of Advanced Materials, Nanjing Tech University, 30 South Puzhu Road, Nanjing, 211816, China

2. School of Chemistry and Chemical Engineering, Shanghai Key Lab of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Abstract

Terminal flexible chains in homoleptic tris-Ir(iii) complexes from ethylhexyl carboxylic ester to hexyl induced dramatic differences in absorption and emission, and in particular had an opposite effect in ternary organic solar cells.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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