Linker dependent symmetry breaking charge separation in 9,10-bis(phenylethynyl)anthracene dimers-Reference-Cited by-同舟云学术

Linker dependent symmetry breaking charge separation in 9,10-bis(phenylethynyl)anthracene dimers

Published:2022 Issue:6 Volume:6 Page:707-717
ISSN:2052-1537
Container-title:Materials Chemistry Frontiers
language:en
Short-container-title:Mater. Chem. Front.

Author:

Su Pengkun¹,Liu Heyuan¹,Shen Li²,Zhou Jun¹,Wang Weijie¹,Liu Shanshan¹,Nie Xinyu¹,Li Zhi³,Liu Zhaobin³,Chen Yanli¹^ORCID,Li Xiyou¹^ORCID

Affiliation:

1. School of Materials Science and Engineering, College of New Energy, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, China

2. College of Chemical Engineering and Environmental Chemistry, Weifang University, Weifang 261061, China

3. Shandong Energy Group Co., Ltd, Jinan, Shandong, 250014, China

Abstract

Fast symmetry breaking charge separation (SB-CS) rate and slow CS recombination rate were achieved simultaneously via tuning the molecular geometry.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QM/D1QM01376A

Reference48 articles.

1. Structural Changes Accompanying Intramolecular Electron Transfer: Focus on Twisted Intramolecular Charge-Transfer States and Structures

2. Charge-transfer rates in symmetric and symmetry-disturbed derivatives of 9,9'-bianthryl

3. Photoinduced Symmetry-Breaking Charge Separation

4. Mixed Electronic States in Molecular Dimers: Connecting Singlet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer

5. Simulation of optical spectra from the reaction center of Rb. sphaeroides. Effects of an internal charge-separated state of the special pair

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3. Triplet Formation in a 9,10-Bis(phenylethynyl)anthracene Dimer and Trimer Occurs by Charge Recombination Rather than Singlet Fission;The Journal of Physical Chemistry Letters;2023-08-29

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