Ruthenium and osmium complexes of hemilabile chiral monophosphinite ligands derived from 1D-pinitol or 1D-chiro-inositol as catalysts for asymmetric hydrogenation reactions
Author:
Affiliation:
1. School of Chemical Sciences
2. University of Auckland
3. Auckland 1142, New Zealand
4. A Industrial Research Limited
5. Lower Hutt, New Zealand
Abstract
Chiral monophosphinite ligands derived from 1D-pinitol or 1D-chiro-inositol coordinate to ruthenium as bidentate hemilabile ligands to produce ketone hydrogenation catalysts that give high conversions but low %ee values.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02558J
Reference53 articles.
1. H. U. Blaser and E.Schmidt , Asymmetric Catalysis on Industrial Scale , Wiley-VCH GmbH & Co. KGaA , Weinheim , 2004
2. Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
3. The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
4. Mechanism of the Hydrogenation of Ketones Catalyzed by trans-Dihydrido(diamine)ruthenium(II) Complexes
5. C1 and C2-symmetric carbohydrate phosphorus ligands in asymmetric catalysis
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