Syntheses and structural characterization of a series of hydrido osmium–palladium carbonyl clusters: [Os5Pd(CO)16Hn+4(µ-Cl)2 –n](n= 0–2), [{Os3Pd(CO)9(µ-H)2(µ-Cl)}2(µ-Cl)2]·H2O and [Os4Pd(CO)11(µ-H)3(µ-Cl)3(C5H5N)]·0.5C6H14-Reference-Cited by-同舟云学术

Syntheses and structural characterization of a series of hydrido osmium–palladium carbonyl clusters: [Os5Pd(CO)16Hn+4(µ-Cl)2 –n](n= 0–2), [{Os3Pd(CO)9(µ-H)2(µ-Cl)}2(µ-Cl)2]·H2O and [Os4Pd(CO)11(µ-H)3(µ-Cl)3(C5H5N)]·0.5C6H14

Published:1995 Issue:24 Volume: Page:3987-3994
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Chan Suzanna,Wong Wing-Tak

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950003987

Reference41 articles.

1. Hydrogen-rich metal cluster complexes. Hexahydrido platinum-osmium carbonyl cluster complexes from the reaction of Pt2Os4(CO)18 with hydrogen

2. Cluster synthesis. 32. Hydrogen-rich metal cluster complexes from the reaction of octadecacarbonyltetraosmiumdiplatinum with hydrogen. Synthesis and molecular structures of PtOs5(CO)16(.mu.-H)6, Pt2Os5(CO)17(.mu.-H)6, PtOs6(CO)18(.mu.-H)8, and Pt2Os7(CO)23(.mu.-H)8

3. Cluster synthesis. 33. New platinum-osmium carbonyl cluster complexes from Pt2Os5(CO)17(.mu.-H)6: synthesis and characterization of PtOs5(CO)15(.mu.3-S)(.mu.-H)6, PtOs5(CO)18(.mu.-H)4, and PtOs4(CO)15(.mu.-H)2

4. Chemistry of the metal carbonyls. Part 77. Some reactions of the platinumtriosmium complexes [Os3Pt(µ-H)2(CO)10(PR3)] with donor molecules; X-ray crystal structures of [Os3Pt(µ-H)2(CO)10(PPh3)2] and [OsPt2(CO)5(PPh3)2(µ3-MeC2Me)]

5. A reversible metal framework rearrangement in high-nuclearity osmium–platinum cluster compounds. X-Ray crystal structures of [Os6Pt(CO)17(µ3-NCMe)(C8H12)], [Os6Pt(CO)17(µ4-NCMe)(C8H12)](C8H12= cyclo-octa-1,5-diene), and [Os6(CO)19(µ3-NCMe)]: compounds with novel metal–acetonitrile bonding modes

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