Formation of η2-aroyl, η1-halogenocarbyne or sterically crowded aryldiazenide ligands in the reactions of ring-substituted tricarbonyl[hydrotris(pyrazolyl)borato]-molybdate and -tungstate anions with arenediazonium cations and related oxidants
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950001709
Reference68 articles.
1. Organonitrogen Derivatives of Metal Carbonyls. II. Arylazo Derivatives of Molybdenum
2. Transition metal tris(1-pyrazolyl)borates containing nitroso and arylazo ligands
3. Anomalous reactions of sterically hindered molybdenum carbonyl anions
4. An unusual effect of ligand methyl-substitution in the reaction of tricarbonyl (Group 6Ametal)[hydrotris(3,5-R2-1-pyrazolyl)borato]anions (R = H, Me) with arenediazonium cations: X-ray crystallographic characterisation of a MoIIη2-aroyl complex, [Mo(η2-COC6H4Me-p)(CO)2{HB(3,5-Me2C3HN2)3}] and of an η2-hexahydrobenzoyl analogue, [Mo(η2-COC6H11)(CO)2{HB(3,5-Me2C3HN2)3}]
5. A new carbyne ligand; synthesis of novel MIV(M = Mo, W) complexes containing terminal halogenomethylidyne ligands: X-ray crystallographic characterisation of η1-chloromethylidyne(dicarbonyl)[tetrakis(1-pyrazolyl)borato]molybdenum(IV)
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