Reactivity patterns of the unsaturated tetrahedral cluster [Re4(µ3-H)4(CO)12]. Easy addition of four MeCN molecules and ‘ionic’ or ‘neutral’ fragmentation pathways of the spiked-triangle intermediate [Re4(µ-H)4(CO)12(NCMe)4]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950002407
Reference27 articles.
1. Preparation and properties of H4Re4(CO)12, an unsaturated polynuclear carbonyl hydride cluster
2. The molecular structure of dodecacarbonyltetra-.mu.3-hydrotetrarhenium. Evidence for face-bridging hydrogen atoms
3. The reaction between unsaturated tetrarhenium cluster H4Re4(CO)12 and tris(diphenylphosphino)methane
4. The reaction between the tetrahydridodecacarbonyltetrarhenium cluster and methanol: a fifth-order reaction
5. Preparation and structure of a non-carbide-stabilized octahedral rhenium cluster: [NEt4][Re6H7(CO)18]
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