Partial deuteriation studies, ethyl-group geometries and C–H bond properties in [MEt(cp)(CO)2](M = Fe or Ru) and [MEt(cp)(CO)3](M = Mo or W)(cp =η5-C5H5)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950003963
Reference32 articles.
1. Carbon–hydrogen bond properties and alkyl group geometries in dichloro(η5-cyclopentadienyl)-methyltitanium(IV) and dichloro(η5-cyclopentadienyl)-ethyltitanium(IV)[TiR(η5-C5H5)Cl2](R = Me or Et)
2. Methyl group geometries, C–H bond properties and internal rotation in dicarbonyl(η5-cyclopentadienyl)methyl-iron(II) and -ruthenium(II), [MMe(η5-C5H5)(CO)2](M = Fe or Ru)
3. Isolated CH stretching frequencies, methyl group geometry, and methyl CH bond lengths and strengths in tricarbonyl(η5-cyclopentadienyl)methyl-chromium(II), -molybdenum(II), and -tungsten(II)
4. Infrared spectra of MeTiCl3 species, methyl group geometry and a force field
5. Infrared spectra and methyl group properties in dicyclopentadienyldimethyl-titanium(IV), -zirconium(IV) and -hafnium(IV)
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1. References;Vibrational Spectra of Organometallics;2018-12-07
2. Tungsten Compounds with CO or Isocyanides;Comprehensive Organometallic Chemistry III;2007
3. Molybdenum Compounds with CO or Isocyanides;Comprehensive Organometallic Chemistry III;2007
4. Agostic Interactions in d0 Metal Alkyl Complexes;Angewandte Chemie International Edition;2004-03-26
5. Experimental and density functional theory studies of ethyltrichlorotitanium, EtTiCl3 and of the ethyl group in EtTiCl3 complexes: Vibrational properties of a β-agostic ethyl ligand;Physical Chemistry Chemical Physics;2001
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