Synthesis, structure and highly selective C3H8/CH4 and C2H6/CH4 adsorption of a (4,8)-c ternary flu-metal–organic framework based upon both [Sc4O2(COO)8] and [Cu4OCl6] clusters-Reference-Cited by-同舟云学术

Synthesis, structure and highly selective C₃H₈/CH₄ and C₂H₆/CH₄ adsorption of a (4,8)-c ternary flu-metal–organic framework based upon both [Sc₄O₂(COO)₈] and [Cu₄OCl₆] clusters

Published:2022 Issue:13 Volume:24 Page:2388-2392
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Ding Min¹,Wang Qian¹²,Cheng Hongtao¹,Bai Junfeng¹^ORCID

Affiliation:

1. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, PR China

2. State Key Laboratory of Coordination Chemistry, School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210093, PR China

Abstract

A new ternary flu-MOF based upon both the torsional cubic 8-c [Sc4O2(COO)8] cluster and the tetrahedral 4-c [Cu4OCl6] cluster has been successfully synthesized and exhibits highly selective C3H8/CH4 and C2H6/CH4 adsorption.

Funder

National Natural Science Foundation of China

Changjiang Scholar Program of Chinese Ministry of Education

Shanxi Province Hundred Talents Project

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00133K

Reference56 articles.