Gold(iii) assisted C–H activation of 1,4,7-trithiacyclononane: synthesis and spontaneous resolution of a bicyclic chiral sulfonium salt
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. St. Catherine University
3. St. Paul, USA
Abstract
A trithiamacrocyclic ligand complex of Au(iii) undergoes a redox-mediated thermal reaction to form a chiral bicyclic sulfonium salt.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53545B
Reference29 articles.
1. Structural and electrochemical studies on trithia macrocyclic complexes of palladium
2. Stabilisation of mononuclear palladium(III). The single crystal X-ray structure of the [Pd(L)2]3+cation (L = 1,4,7-trithiacyclononane)
3. The structural characterisation and elucidation of the electronic structure of the mononuclear Pt(iii) complex [Pt([9]aneS3)2]3+ ([9]aneS3 = 1,4,7-trithiacyclononane)
4. Crystallographic, Electrochemical, and Electronic Structure Studies of the Mononuclear Complexes of Au(I)/(II)/(III) with [9]aneS2O ([9]aneS2O = 1-oxa-4,7-dithiacyclononane)
5. Redox Non-innocence of Thioether Macrocycles: Elucidation of the Electronic Structures of Mononuclear Complexes of Gold(II) and Silver(II)
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1. Bicyclic Systems With Bridgehead (Ring Junction) Sulfur, Selenium, or Tellurium Atoms;Comprehensive Heterocyclic Chemistry IV;2022
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