Pu(<scp>iii</scp>) and Cm(<scp>iii</scp>) in the presence of EDTA: aqueous speciation, redox behavior, and the impact of Ca(<scp>ii</scp>)-Reference-Cited by-同舟云学术

Pu(iii) and Cm(iii) in the presence of EDTA: aqueous speciation, redox behavior, and the impact of Ca(ii)

Published:2022 Issue:15 Volume:12 Page:9478-9493
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

DiBlasi Nicole A.¹²^ORCID,Tasi Agost G.²^ORCID,Trumm Michael²^ORCID,Schnurr Andreas²,Gaona Xavier²^ORCID,Fellhauer David²,Dardenne Kathy²^ORCID,Rothe Jörg²,Reed Donald T.³,Hixon Amy E.¹^ORCID,Altmaier Marcus²

Affiliation:

1. Department of Civil & Environmental Engineering & Earth Sciences, University of Notre Dame, 301 Stinson-Remick, Notre Dame, IN 46556, USA

2. Karlsruhe Institute of Technology, Institute for Nuclear Waste Disposal, P.O. Box 3640, Karlsruhe, 76021, Germany

3. Los Alamos National Laboratory, 1400 University Dr., Carlsbad, NM 88220, USA

Abstract

Combined advanced spectroscopy and solubility studies provide evidence for the formation of novel calcium-containing and hydrolyzed (Cm,Pu)(iii)–EDTA complex(es).

Funder

U.S. Department of Energy

Karlsruhe Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA09010K

Reference95 articles.

1. H.Geckeis , M.Zavarin , B.Salbu , O. C.Lind and L.Skipperud , in Chemistry , American Nuclear Society , La Grange Park, IL, USA , 2nd edn, 2019 , vol. 4

2. IAEA , Scientific and Technical Basis for the Geologic Disposal of Radioactive Wastes , International Atomic Energy Agency , Vienna, Austria , 2003

3. Long-term cement corrosion in chloride-rich solutions relevant to radioactive waste disposal in rock salt – Leaching experiments and thermodynamic simulations

4. Appendix SOTERM-2019 Actinide Chemistry Source Term , United States Department of Energy , 2019 , https://wipp.energy.gov/library/CRA/CRA%202019/index.html

5. NEA , Confidence in the Long-term Safety of Deep Geological Repositories: Its Development and Communication , OECD/NEA , Paris, France , 1999

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