Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO<sub>2</sub>towards catalytic<i>N</i>-methylation-Reference-Cited by-同舟云学术

Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO₂towards catalyticN-methylation

Published:2023 Issue:19 Volume:14 Page:5079-5086
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gautam Nimisha¹^ORCID,Logdi Ratan¹,P. Sreejyothi¹,Roy Antara²,Tiwari Ashwani K.¹^ORCID,Mandal Swadhin K.¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, Nadia, 741246, West Bengal, India

2. Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, 721302, West Bengal, India

Abstract

This work reports the first catalyticN-methylation of primary amides using CO2. BICAAC plays a dual role in activating the amide and CO2during catalysis.

Funder

Indian Institute of Science Education and Research Kolkata

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01216F

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