Dynamic redox cycle of Cu0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation-Reference-Cited by-同舟云学术

Dynamic redox cycle of Cu0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation

Published:2015 Issue:47 Volume:5 Page:37581-37584
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ma Xiangang¹²³⁴⁵,Yang Zhiqiang⁶⁷⁴⁵,Liu Xuebin⁶⁷⁴⁵,Tan Xingzhi⁶⁷⁴⁵,Ge Qingjie¹²³⁴⁵

Affiliation:

1. Dalian National Laboratory for Clean Energy

2. Dalian Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Dalian 116023

5. P. R. China

6. Energy Innovation Laboratory

7. BP (China) Holdings Limited

Abstract

Esters can oxidize Cu⁰ to Cu⁺ and the obtained Cu⁺ can be reduced back to Cu⁰ by H₂ under reaction conditions. Cu⁰ and Cu⁺ are in a dynamic cycle during ester hydrogenation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA04389A

Reference23 articles.

1. Effect of feedstock solvent on the stability of Cu/SiO2catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol

2. Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol

3. Ester hydrogenolysis over promoted Cu/SiO2 catalysts

4. Hydrogenolysis of Dimethyl Maleate on Cu/ZnO/Al2O3 Catalysts

5. Synthesis of Ethanol via Syngas on Cu/SiO2 Catalysts with Balanced Cu0–Cu+ Sites

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