Singlet ground states in compounds with a [MnIII4O2]8+ core due to broken degeneration-Reference-Cited by-同舟云学术

Singlet ground states in compounds with a [MnIII4O2]8+ core due to broken degeneration

Published:2017 Issue:8 Volume:41 Page:2934-2940
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Escriche-Tur Luis¹²³⁴⁵^ORCID,Albela Belén⁵⁶⁷⁸⁹,Font-Bardia Mercè¹⁰¹¹²³⁴,Corbella Montserrat¹²³⁴¹²

Affiliation:

1. Departament de Química Inorgànica i Orgànica (Secció inorgánica)

2. Universitat de Barcelona

3. 08028 Barcelona

4. Spain

5. Laboratoire de Chimie

6. ENS de Lyon

7. Université de Lyon

8. 69364 Lyon Cedex 07

9. France

10. Cristal·lografia

11. Mineralogia i Dipòsits Minerals

12. Institud de Nanociència i Nanotecnologia de la Universitat de Barcelona (IN2UB)

Abstract

Energy distribution of spin states depending on the distinction between the magnetic interactions. Singlet ground states due to broken degeneration of S_T ≠ 0 states. Attempt to assign spin states to a particular spin configuration.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03845J

Reference33 articles.

1. Manganese Clusters with Relevance to Photosystem II

2. Two New Mixed-Valence Manganese Complexes of Formula [Mn4O2(X-benzoato)7(bpy)2] (X = 2-Cl, 2-Br) and the Crystal Structure of the 2-Cl Complex: Ground-State Spin Variability in the [Mn4O2]7+ Complexes

3. Modeling the photosynthetic water oxidation center. Preparation and properties of tetranuclear manganese complexes containing [Mn4O2]6+,7+,8+ cores, and the crystal structures of Mn4O2(O2CMe)6(bipy)2 and [Mn4O2(O2CMe)7(bipy)2](ClO4)

4. Single-Molecule Magnets

5. Preparation, crystal structure and chelate substitution reactions of [Mn4O2(O2CPh)6(dpm)2] (dpm=the anion of dipivaloylmethane)

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