Few-layer black phosphorus enables nitrogen fixation under ambient conditions-Reference-Cited by-同舟云学术

Few-layer black phosphorus enables nitrogen fixation under ambient conditions

Published:2024 Issue:7 Volume:14 Page:4742-4747
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Garnes-Portolés Francisco¹,Lloret Vicent²³,Vidal-Moya José Alejandro¹,Löffler Mario³⁴^ORCID,Mayrhofer Karl J. J.³⁴^ORCID,Cerón-Carrasco Jose Pedro⁵^ORCID,Abellán Gonzalo⁶^ORCID,Leyva-Pérez Antonio¹^ORCID

Affiliation:

1. Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022, Valencia, Spain

2. Department of Chemistry and Pharmacy, Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestrasse 42, 91054 Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany

3. Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy (IEK-11), Forschungszentrum Jülich GmbH, Cauerstr. 1, 91058 Erlangen, Germany

4. Department of Chemical and Biological Engineering, Friedrich-Alexander University Erlangen-Nürnberg, Cauerstr. 1, 91058 Erlangen, Germany

5. Centro Universitario de la Defensa, Academia General del Aire, Universidad Politécnica de Cartagena, C/ Coronel López Peña S/N, Santiago de La Ribera, 30720 Murcia, Spain

6. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980, Paterna, Valencia, Spain

Abstract

Nitrogen fixation occurs spontaneously during the oxidation of elemental phosphorus under ambient conditions, although in low extent (<0.01 wt%). However, this discovery could have implications in the chemistry of these two basic elements.

Funder

Generalitat Valenciana

FP7 Ideas: European Research Council

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D3RA07331A

Reference34 articles.

1. Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions

2. Coupling dinitrogen and hydrocarbons through aryl migration

3. Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

4. Reduction of N2 by supported tungsten clusters gives a model of the process by nitrogenase

5. Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst