Effect of substituents on surface equilibria of thiophenols and isoquinolines on gold substrates studied using surface-enhanced Raman spectroscopy

Author:

Emmons Erik D.1234,Guicheteau Jason A.1234ORCID,Fountain Augustus W.1234,Tripathi Ashish1234ORCID

Affiliation:

1. Research and Technology Directorate

2. U.S. Army CCDC Chemical Biological Center

3. Aberdeen Proving Ground

4. USA

Abstract

The effect of substituents on the surface adsorption equilibria on gold substrates was studied using surface-enhanced Raman spectroscopy in order to determine the effects of the localized dipole moments and charge donating/withdrawing properties on the binding affinity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference54 articles.

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4. Profiling the Near Field of a Plasmonic Nanoparticle with Raman-Based Molecular Rulers

5. Kinetics and Reaction Mechanisms of Thiophenol Adsorption on Gold Studied by Surface-Enhanced Raman Spectroscopy

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