Tuning the morphology and chemical distribution of Ag atoms in Au rich nanoparticles using electrochemical dealloying

Author:

Dworzak Alexandra12ORCID,Paciok Paul3ORCID,Mahr Christoph45ORCID,Heggen Marc3ORCID,Dosche Carsten2ORCID,Rosenauer Andreas45ORCID,Oezaslan Mehtap12ORCID

Affiliation:

1. Technical Electrocatalysis Laboratory, Institute of Technical Chemistry, Technische Universität Braunschweig, Franz-Liszt-Str. 35a, 38106 Braunschweig, Germany

2. Institute of Chemistry, Carl von Ossietzky University of Oldenburg, Carl-von-Ossietzky-Str. 9-11, 26129 Oldenburg, Germany

3. Ernst Ruska-Center, Jülich Research Centre, 52425 Jülich, Germany

4. Institute of Solid State Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany

5. MAPEX Center for Materials and Processes, University of Bremen, Bibliothekstr. 1, 28359 Bremen, Germany

Abstract

Dealloying of Ag–Au nanoparticles strongly differs from bulk alloys and is controlled by electrochemical conditions and Au surface atom mobility.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

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