P-Functionalized tetrathiafulvalenes from 1,3-dithiole-2-thiones?-Reference-Cited by-同舟云学术

P-Functionalized tetrathiafulvalenes from 1,3-dithiole-2-thiones?

Published:2020 Issue:39 Volume:44 Page:17122-17128
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Gese A.¹²³⁴,Akter M.¹²³⁴,Schnakenburg G.¹²³⁴,García Alcaraz A.⁵⁶⁷⁸⁹,Espinosa Ferao A.⁵⁶⁷⁸⁹^ORCID,Streubel R.¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Rheinische Friedrich-Wilhelms-Universität Bonn

3. 53121 Bonn

4. Germany

5. Departamento de Química Orgánica

6. Facultad de Química

7. Universidad de Murcia

8. Campus de Espinardo

9. 30100 Murcia

Abstract

Synthesis of mono- and bisphosphanylated 1,3-dithiole-2-thiones is presented, including phosphite-mediated reductive C,C coupling reactions. Computational studies point to a spirothiaphosphirane and a S-heterocyclic carbene as key intermediates.

Funder

Rheinische Friedrich-Wilhelms-Universität Bonn

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02984J

Reference24 articles.

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4. Preparation of Tetrathiafulvalenes (TTF) and their Selenium Analogs -Tetraselenafulvalenes (TSeF)

5. Bis- and tetrakis-(diphenylphosphino) tetrathiafulvalenes as precursors of redox-active organic—inorganic polymeric networks

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