Cyanide–alkene competition in a diiron complex and isolation of a multisite (cyano)alkylidene

Cyanide–alkene competition in a diiron complex and isolation of a multisite (cyano)alkylidene–alkene species

Published:2022 Issue:5 Volume:51 Page:1936-1945
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bresciani Giulio¹²,Schoch Silvia¹²,Biancalana Lorenzo¹²^ORCID,Zacchini Stefano²³^ORCID,Bortoluzzi Marco²⁴^ORCID,Pampaloni Guido¹²^ORCID,Marchetti Fabio¹²^ORCID

Affiliation:

1. University of Pisa, Department of Chemistry and Industrial Chemistry, Via G. Moruzzi 13, I-56124 Pisa, Italy

2. CIRCC, Via Celso Ulpiani 27, I-70126 Bari, Italy

3. University of Bologna, Department of Industrial Chemistry “Toso Montanari”, Viale Risorgimento 4, I-40136 Bologna, Italy

4. University of Venezia “Ca’ Foscari”, Department of Molecular Science and Nanosystems, Via Torino 155, I-30170 Mestre, VE, Italy

Abstract

A cyanide addition/decarbonylation sequence in a diiron (allyl)amino-alkylidyne complex results in the formation of an unusual alkylidene–alkenyl species as an isolable intermediate along the route leading to stable metal coordination of the cyanide.

Funder

Università di Pisa

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03781A

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