Stable mixed-valence diphenylphosphanido bridged platinum(ii)–platinum(iv) complexes
Author:
Affiliation:
1. Departamento de Química Inorgánica
2. Instituto de Síntesis Química y Catálisis Homogénea-ISQCH
3. Universidad de Zaragoza-C.S.I.C.
4. E-50009 Zaragoza
5. Spain
6. DICATECh
7. Politecnico di Bari
8. I-70125 Bari
9. Italy
Abstract
New phosphido complexes displaying Pt in +4 oxidation state are described.
Funder
Ministerio de Economía y Competitividad
Gobierno de Aragón
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00712A
Reference79 articles.
1. Structure and protonation of the bis-ethylene adduct [Pt(μ-PBut2)(η2-CH2CH2)]2. Pt–H–P agostic interaction and proton scrambling
2. Synthesis and Characterization of New Triangulo Derivatives of PtIPtIPtII, Including the First Platinum Cluster Binding Both Ethylene and CO
3. The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure We thank the Ministero dell'Università e della Ricerca Scientifica e Tecnologica (MURST), Programmi di Interesse Nazionale, 2000–2001, for financial support.
4. Stable η1-Alkynyl−μ,η1:η2-Alkenyl Complexes from the Reaction of Terminal Alkynes with Encumbered Dinuclear Platinum Compounds and Their Formyl, Methoxycarbonyl, and Hydride Derivatives
5. Reactions of trinuclear platinum clusters with electrophiles: ionisation isomerism with [Pt3(μ2-I)(μ-PPh2)2(PPh3)3]I and [Pt3(μ-PPh2)2I2(PPh3)3]. Structures of [Pt3(μ2-Cl)(μ-PPh2)2(PPh3)3]PF6, [Pt3(μ-PPh2)2I2(PPh3)3] and of the Pt–Ag cluster [Pt3{μ3-AgBF4}(μ2-I)(μ-PPh2)2(PPh3)3]BF4
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