Efficient glycolysis of PET catalyzed by a metal-free phosphazene base: the important role of EG<sup>−</sup>-Reference-Cited by-同舟云学术

Efficient glycolysis of PET catalyzed by a metal-free phosphazene base: the important role of EG⁻

Published:2022 Issue:3 Volume:24 Page:1294-1301
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Fan Chumeng¹,Zhang Lei²,Zhu Chenxi¹,Cao Jingjing¹,Xu Yunlong¹,Sun Ping¹,Zeng Guixiang³^ORCID,Jiang Wei¹^ORCID,Zhang Quanxing¹

Affiliation:

1. State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

2. Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

3. Kuang Yaming Honors School & Institute for Brain Sciences, Nanjing University, Nanjing 210023, China

Abstract

A new kind of efficient metal-free catalyst phosphazene base (t-BuP2) was developed, which could achieve 100% conversion of PET and obtain comparable BHET yield (92.7%) to metal-based catalysts.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D1GC03885K

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