Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system-Reference-Cited by-同舟云学术

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Published:2016 Issue:85 Volume:52 Page:12653-12656
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Manson Jamie L.¹²³⁴,Schlueter John A.⁵⁶⁷⁴,Garrett Kerry E.¹²³⁴,Goddard Paul A.⁸⁹¹⁰¹¹,Lancaster Tom¹²¹³¹⁴¹¹,Möller Johannes S.¹⁵⁸¹⁶¹⁷¹¹,Blundell Stephen J.¹⁵⁸¹⁶¹⁷¹¹,Steele Andrew J.¹⁵⁸¹⁶¹⁷¹¹,Franke Isabel¹⁵⁸¹⁶¹⁷¹¹,Pratt Francis L.¹⁸¹⁹²⁰¹¹,Singleton John²¹²²²³⁴,Bendix Jesper²⁴²⁵²⁶²⁷,Lapidus Saul H.²⁸²⁹⁶³⁰⁴,Uhlarz Marc³¹³²³³³⁴,Ayala-Valenzuela Oscar²¹²²²³⁴,McDonald Ross D.²¹²²²³⁴,Gurak Mary²¹²²²³⁴,Baines Christopher³⁵³⁶³⁷³⁸

Affiliation:

1. Department of Chemistry and Biochemistry

2. Eastern Washington University

3. Cheney

4. USA

5. Materials Science Division

6. Argonne National Laboratory

7. Argonne

8. Department of Physics

9. University of Warwick

10. Coventry CV4 7AL

11. UK

12. Center for Materials Physics

13. Durham University

14. Durham DH1 3LE

15. Clarendon Laboratory

16. University of Oxford

17. Oxford OX1 3PU

18. ISIS Pulsed-Muon Facility

19. STFC Rutherford Appleton Laboratory

20. Oxfordshire OX11 0QX

21. National High Magnetic Field Laboratory

22. Los Alamos National Laboratory

23. Los Alamos

24. Department of Chemistry

25. University of Copenhagen

26. Copenhagen DK-2100

27. Denmark

28. X-ray Science Division

29. Advanced Photon Source

30. Lemont IL 60439

31. Hochfeld-Magnetlabor Dresden (HLD-EMFL)

32. Helmholtz-Zentrum Dresden Rossendorf

33. Dresden

34. Germany

35. Laboratory for Muon-Spin Spectroscopy

36. Paul Scherrer Institut

37. CH-5232 Villigen PSI

38. Switzerland

Abstract

These bimetallic MOFs contain [Cu(pyz)₂]²⁺ sheets and MF₆ⁿ⁻ octahedra whereby only the Cu(ii) moments magnetically order.

Funder

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC05873F

Reference20 articles.

1. Magnetism: Molecules to Materials, ed. J. S. Miller and M. Drillon, Wiley-VCH, Weinheim, 2002–2004, vol. 1–5, and references therein

2. Crystal structure and magnetic characterization of [C(NH2)3]3FeF6

3. Synthesis, structure of [H3dien]·(MF6)·H2O (M=Cr, Fe) and 57Fe Mössbauer study of [H3dien]·(FeF6)·H2O

4. Hydrothermal chemistry of oligomeric vanadium oxyfluorides

5. Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes

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