First structural characterization of Pa(iv) in aqueous solution and quantum chemical investigations of the tetravalent actinides up to Bk(iv): the evidence of a curium break-Reference-Cited by-同舟云学术

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First structural characterization of Pa(iv) in aqueous solution and quantum chemical investigations of the tetravalent actinides up to Bk(iv): the evidence of a curium break

Published:2016 Issue:2 Volume:45 Page:453-457
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Banik Nidhu lal¹²³⁴,Vallet Valérie⁵⁶⁷⁸⁹,Réal Florent⁵⁶⁷⁸⁹,Belmecheri Réda Mohamed¹⁰¹¹¹²¹³,Schimmelpfennig Bernd¹²³⁴,Rothe Jörg¹²³⁴,Marsac Rémi¹²³⁴,Lindqvist-Reis Patric¹²³⁴,Walther Clemens¹⁴¹⁵¹⁶⁴,Denecke Melissa A.¹⁷¹⁸¹⁹²⁰,Marquardt Christian M.¹²³⁴

Affiliation:

1. Institut für Nukleare Entsorgung

2. Karlsruhe Institute of Technology

3. 76021 Karlsruhe

4. Germany

5. Laboratoire PhLAM

6. UMR-CNRS 8523

7. Université Lille 1 (Sciences et Technologies)

8. F-59655 Villeneuve d'Ascq

9. France

10. Laboratoire de Thermodynamique et Modélisation Moléculaire

11. Faculté de Chimie

12. 16111 Bab-Ezzouar

13. Algeria

14. Institut für Radioökologie und Strahlenschutz

15. Leibniz Universität Hannover

16. Hannover

17. Dalton Nuclear Institute

18. The University of Manchester

19. Manchester

20. UK

Abstract

The Pa⁴⁺ aqua ion is nine-coordinated like the other early tetravalent actinides whereas a change to eight-coordination occurs at curium.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03560K

Reference46 articles.

1. �ber die komplexe Nature des UrX

2. Persistent export of 231Pa from the deep central Arctic Ocean over the past 35,000 years

3. Reversed flow of Atlantic deep water during the Last Glacial Maximum

4. Collapse and rapid resumption of Atlantic meridional circulation linked to deglacial climate changes

5. Similar rates of modern and last-glacial ocean thermohaline circulation inferred from radiochemical data

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