Mechanistic interpretation of selective catalytic hydrogenation and isomerization of alkenes and dienes by ligand deactivated Pd nanoparticles
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. California State University
3. Long Beach
4. Long Beach, 90840 USA
Abstract
Unsupported thiolate-capped palladium nanoparticle catalysts are found to be highly substrate-selective for alkene hydrogenation and isomerization.
Funder
Division of Chemistry
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NR/C5NR05090A
Reference39 articles.
1. Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity
2. Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands
3. Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition
4. Biotransformation of Two ent-Pimara-9(11),15-diene Derivatives by Gibberella fujikuroi
5. Regioselective Semihydrogenation of Dienes
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