Modulating the electron-transfer properties of a mixed-valence system through host

Modulating the electron-transfer properties of a mixed-valence system through host–guest chemistry

Published:2015 Issue:2 Volume:6 Page:1334-1340
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zubi Ahmed¹²³⁴,Wragg Ashley¹²³⁴,Turega Simon⁵⁶³⁴,Adams Harry¹²³⁴,Costa Paulo J.⁷⁸⁹¹⁰¹¹,Félix Vítor⁷¹²⁹¹⁰¹¹,Thomas Jim A.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Sheffield

3. Sheffield

4. UK

5. Biomedical Research Centre

6. Sheffield Hallam University

7. Departamento de Química

8. QOPNA and Secção Autónoma de Ciências da Saúde

9. Universidade de Aveiro

10. Aveiro

11. Portugal

12. CICECO and Secção Autónoma de Ciências da Saúde

Abstract

Herein, we report that the interplay between the binding properties and redox activity of a self-assembled trinuclear Ru^II macrocycle leads to an hitherto unreported phenomenon, in which access to specific MV states is gated by host–guest chemistry.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02799J

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