Conformational topography of tris(2-methylbutyl) phosphate and the influence of methyl branching at the non-hyperconjugative carbon on the conformational landscape: insights from matrix isolation infrared spectroscopy and DFT computations-Reference-Cited by-同舟云学术

Conformational topography of tris(2-methylbutyl) phosphate and the influence of methyl branching at the non-hyperconjugative carbon on the conformational landscape: insights from matrix isolation infrared spectroscopy and DFT computations

Published:2020 Issue:42 Volume:22 Page:24372-24392
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sarkar Subramee¹²³⁴⁵,Chandra Swaroop¹²³⁴⁵^ORCID,Suryaprasad B.¹²³⁴⁵,Ramanathan N.¹²³⁴⁵^ORCID,Sundararajan K.¹²³⁴⁵^ORCID,Suresh A.¹²³⁴⁵

Affiliation:

1. Homi Bhabha National Institute

2. Materials Chemistry and Metal Fuel Cycle Group

3. Indira Gandhi Centre for Atomic Research

4. Kalpakkam 603 102

5. India

Abstract

Branching dramatically reduces the number of conformers of T2MBP relative to its straight chain analogue, while hyperconjugative effects stabilize 'gauche' over 'trans' form, energetically.

Funder

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03403G

Reference77 articles.

1. V. S. Kislik , Solvent Extraction: Classical and Novel Approaches, 2012

2. The Effect of the Structure of Trialkyl Phosphates on their Physicochemical Properties and Extraction Behavior

3. Extraction Behaviour of Tris(2-methylbutyl) Phosphate with Fission Products and Heavy Metal Ions

4. A REVIEW OF THIRD PHASE FORMATION IN EXTRACTION OF ACTINIDES BY NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS

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