Sequential olefination–dimerisation of benzylic dithioacetals by the nickel-catalysed reaction with methyl Grignard or zinc reagent-Reference-Cited by-同舟云学术

Sequential olefination–dimerisation of benzylic dithioacetals by the nickel-catalysed reaction with methyl Grignard or zinc reagent

Published:2022 Issue:16 Volume:12 Page:9653-9659
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yu Lei¹,Lai Guo-Qiao¹,Zhang Pinglu¹,Li Ze¹,Luh Tien-Yau²^ORCID

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry, and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China

2. Department of Chemistry, National Taiwan University, Taipei, Taiwan 10617

Abstract

The nickel-catalyzed olefination of benzylic dithioacetal with MeMgI or the corresponding zinc reagent generates Mg(ii) or Zn(ii) mercaptide which converts 2-arylpropene into dimer regioselectively.

Funder

Hangzhou Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA00841F

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3. J. Cossy , Grignard reagents and transition metal catalysts: formation of C-C Bonds by Cross Coupling , de Gruyter , 2016

4. Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes

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