A computational study on the N-heterocyclic carbene-catalyzed Csp2–Csp3 bond activation/[4+2] cycloaddition cascade reaction of cyclobutenones with imines: a new application of the conservation principle of molecular orbital symmetry-Reference-Cited by-同舟云学术

A computational study on the N-heterocyclic carbene-catalyzed Csp2–Csp3 bond activation/[4+2] cycloaddition cascade reaction of cyclobutenones with imines: a new application of the conservation principle of molecular orbital symmetry

Published:2016 Issue:29 Volume:18 Page:19933-19943
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Yang¹²³⁴⁵,Wu Bohua¹²³⁴⁵,Zhang Haoyang¹²³⁴⁵,Wei Donghui¹²³⁴⁵,Tang Mingsheng¹²³⁴⁵

Affiliation:

1. The College of Chemistry and Molecular Engineering

2. Center of Computational Chemistry

3. Zhengzhou University

4. Zhengzhou

5. P. R. China

Abstract

A new application of the conservation principle of molecular orbital symmetry has been suggested for disclosing the role of NHC.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03180C

Reference54 articles.

1. Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

2. Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

3. Synthesis of metallacyclopentenones by insertion of rhodium into cyclobutenones

4. Reaction of cyclobutenones with low-valent metal reagents to form .eta.4- and .eta.2-vinylketene complexes. Reaction of .eta.4-vinylketene complexes with alkynes to form phenols

5. Insertion of (.eta.5-indeny)cobalt(I) into cyclobutenones: the first synthesis of phenols from isolated vinylketene complexes

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