Effect of distal metal species on lewis basicity of a μ3-oxo ligand in a doubly oxo-bridged (μ3-O)[Rh(cod)]3(μ4-O)M core-Reference-Cited by-同舟云学术

Effect of distal metal species on lewis basicity of a μ₃-oxo ligand in a doubly oxo-bridged (μ₃-O)[Rh(cod)]₃(μ₄-O)M core

Published:2024 Issue:20 Volume:53 Page:8546-8549
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tsurugi Hayato¹²^ORCID,Mori Hiroki¹,Mori Haruna¹,Nakamoto Masami¹,Tanaka Shinji³^ORCID,Mashima Kazushi⁴^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan

3. Interdisciplinary Research Center for Catalytic Chemistry (IRC3), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan

4. Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

The Lewis basicity of a μ3-oxo ligand for (μ3-O)[Rh(cod)]3(μ4-O)M complexes was controllable by metal species on the μ4-oxo ligand locating at the opposite site of the μ3-oxo ligand.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00932K

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