PdGa/TiO2 an efficient heterogeneous catalyst for direct methylation of N-methylaniline with CO2/H2-Reference-Cited by-同舟云学术

PdGa/TiO2 an efficient heterogeneous catalyst for direct methylation of N-methylaniline with CO2/H2

Published:2016 Issue:105 Volume:6 Page:103650-103656
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Su Xinluona¹²³⁴⁵,Lin Weiwei⁵⁶⁷⁸⁴,Cheng Haiyang⁵⁶⁷⁸⁴,Zhang Chao⁵⁶⁷⁸⁴,Li Yan⁵⁶⁷⁸⁴,Liu Tong⁵⁶⁷⁸⁴,Zhang Bin⁵⁶⁷⁸⁴,Wu Qifan⁵⁶⁷⁸⁴,Yu Xiujuan¹²³⁴,Zhao Fengyu⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Department of Environmental Science and Engineering

2. Heilongjiang University

3. Harbin

4. P. R. China

5. State Key Laboratory of Electroanalytical Chemistry

6. Changchun Institute of Applied Chemistry

7. Chinese Academy of Sciences (CAS)

8. Changchun 130022

Abstract

PdGa/TiO₂ showed excellent catalytic performance in the methylation of amine with CO₂/H₂ as the PdGa bimetallic particles formed on the surface of TiO₂, which could activate CO₂ to form formic acid, an important and active methylation reagent.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22089D

Reference34 articles.

1. Z. Rappoport , The Chemistry of Anilines, Wiley InterScience, 2007

2. K. Weissermel and H. J.Arpe, Industrial Organic Chemistry, Wiley-VCH, Weinheim, 2003