Selective cyclohexene oxidation with O2, H2O2 and tert-butyl hydroperoxide over spray-flame synthesized LaCo1−xFexO3 nanoparticles

Author:

Büker Julia1234,Alkan Baris56784,Fu Qi1234,Xia Wei1234,Schulwitz Jonas1234,Waffel Daniel1234,Falk Tobias1234,Schulz Christof56784,Wiggers Hartmut56784,Muhler Martin12349ORCID,Peng Baoxiang12349ORCID

Affiliation:

1. Laboratory of Industrial Chemistry

2. Ruhr University Bochum

3. 44780 Bochum

4. Germany

5. IVG, Institute for Combustion and Gas Dynamics – Reactive Fluids and CENIDE

6. Center for Nanointegration Duisburg-Essen

7. University of Duisburg-Essen

8. 47057 Duisburg

9. Max Planck Institute for Chemical Energy Conversion

Abstract

A series of spray-flame made LaCo1−xFexO3 nanoparticles showed promising activity for liquid-phase cyclohexene oxidation. Various oxidizing agents, i.e., O2, H2O2 and tert-butyl hydroperoxide, led to different product selectivities.

Funder

Deutsche Forschungsgemeinschaft

Evonik Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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