High pressure behaviour of the organic semiconductor salt (TTF-BTD)2I3

Author:

Montisci Fabio1,Lanza Arianna1ORCID,Fisch Martin1,Sonneville Camille2,Geng Yan1ORCID,Decurtins Silvio1,Reber Christian2ORCID,Liu Shi-Xia1ORCID,Macchi Piero13ORCID

Affiliation:

1. Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland

2. Département de chimie, Université de Montréal, Montréal, QC H3C 3J7, Canada

3. Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Via Mancinelli 7, I-20131 Milan, Italy

Abstract

The high pressure form of the organic semiconductor (TTF-BTD)2I3 is analysed with Raman and XRD and theoretical approaches. Although experimentally a very high-pressure form cannot be obtained, theory predicts the dimerization of TTF-BTD cations.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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