The effect of H2 : N2 ratio on the NH3 synthesis rate and on process economics over the Co3Mo3N catalyst-Reference-Cited by-同舟云学术

The effect of H2 : N2 ratio on the NH3 synthesis rate and on process economics over the Co3Mo3N catalyst

Published:2021 Issue: Volume:229 Page:475-488
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Aslan Mustafa Y.¹²³⁴^ORCID,Hargreaves Justin S. J.⁵⁶⁷⁸^ORCID,Uner Deniz¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Engineering

2. Middle East Technical University

3. Ankara

4. Turkey

5. School of Chemistry

6. University of Glasgow

7. Glasgow G12 8QQ

8. UK

Abstract

Ammonia synthesis rates are independent of H₂ : N₂ stoichiometry for H₂ : N₂ > 0.5 over the Co₃Mo₃N catalyst. Only strongly adsorbed hydrogen is involved in the reaction. Its coverage is independent of hydrogen pressure for H₂ : N₂ > 0.5.

Funder

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/FD/C9FD00136K

Reference49 articles.

1. Energy efficiency improvements in ammonia production—perspectives and uncertainties

2. Ruthenium Nanocatalysts for Ammonia Synthesis: A Review

3. G. Thomas and G.Parks , Energy , 2006 , https://www.energy.gov/sites/prod/files/2015/01/f19/fcto_nh3_h2_storage_white_paper_2006.pdf , accessed: 07-Oct-2019

4. Recent Developments in Nitrogen Reduction Catalysts: A Virtual Issue

5. Techno-economic assessment of CO2 capture at steam methane reforming facilities using commercially available technology

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