Planar tetracoordinate carbon in tungstenacyclobutadiene from alkyne metathesis and expanded structures
Author:
Affiliation:
1. Chemical Sciences and Technology Division
2. CSIR-National Institute for Interdisciplinary Science and Technology
3. Trivandrum 695 019
4. India
5. Academy of Scientific & Innovative Research
Abstract
Establishing the Cβ of tungstenacyclobutadiene (WCBD) as a ptC center paves the way for a new strategy to make novel materials containing multiple ptC centers. The 1-, 2- and 3-dimensional expansion of the WCBD motifs provides access to ptC-incorporated new metal–organic frameworks.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03922C
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