A theoretical approach for homogeneous CO<sub>2</sub> reduction by Ni(cyclam): substituents with intra-molecular hydrogen transfer-Reference-Cited by-同舟云学术

A theoretical approach for homogeneous CO₂ reduction by Ni(cyclam): substituents with intra-molecular hydrogen transfer

Published:2022 Issue:11 Volume:9 Page:2691-2696
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Chen Xin¹,Wang Chiming²,Qi Dongdong²,Xing Xianran¹^ORCID

Affiliation:

1. Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China

2. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China

Abstract

The detailed mechanism reveals the deep relationship of reaction activity with acidity, substituent nature (at position 1 or 2), and conformation in CO2 reduction.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00033D

Reference44 articles.

1. M.Aresta , Carbon Dioxide as Chemical Feedstock , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2010 , pp. 9–11