An air-stable anionic two-dimensional semiconducting metal-thiolate network and its exfoliation into ultrathin few-layer nanosheets

Author:

Zeng Qi1234,Wang Lei1234,Huang Yitao1234,Zheng Sai-Li1234,He Yonghe1234,He Jun1234ORCID,Liao Wei-Ming1234ORCID,Xu Gang56784ORCID,Zeller Matthias9101112,Xu Zhengtao913144ORCID

Affiliation:

1. School of Chemical Engineering and Light Industry

2. Guangdong University of Technology

3. Guangzhou 510006

4. China

5. State Key Laboratory of Structural Chemistry

6. Fujian Institute of Research on the Structure of Matter

7. Chinese Academy of Sciences

8. Fuzhou 350002

9. Department of Chemistry

10. Purdue University

11. West Lafayette

12. USA

13. City University of Hong Kong

14. Kowloon

Abstract

Metal-thiolate networks are topical electronic materials, but hard to crystallize: this one makes big single crystals, and boasts small band gap, stable radical organic linkers, and facile exfoliation into nanosheets.

Funder

National Natural Science Foundation of China

Science and Technology Planning Project of Guangdong Province

City University of Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference59 articles.

1. Computational screening of structural and compositional factors for electrically conductive coordination polymers

2. Z. Xu , Metal–Organic Frameworks: Semiconducting Frameworks , John Wiley & Sons, Ltd , Chichester , 2014

3. Conductive metal–organic frameworks and networks: fact or fantasy?

4. Electrical conductive coordination polymers

5. N. Nidamanuri , K.Maity and S.Saha , Series on Chemistry, Energy and the Environment , 2018 , vol. 2, p. 655

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