Identification of key oxidative intermediates and the function of chromium dopants in PKU-8: catalytic dehydrogenation of sec-alcohols with tert-butylhydroperoxide-Reference-Cited by-同舟云学术

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Identification of key oxidative intermediates and the function of chromium dopants in PKU-8: catalytic dehydrogenation of sec-alcohols with tert-butylhydroperoxide

Published:2021 Issue:4 Volume:11 Page:1365-1374
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wang Weilu¹²³⁴,He Yang⁵⁶⁷⁸,He Junkai⁹¹⁰¹¹⁸^ORCID,Dang Yanliu⁹¹⁰¹¹⁸,Kankanmkapuge Tharindu⁹¹⁰¹¹⁸,Gao Wenliang¹²³⁴^ORCID,Cong Rihong¹²³⁴^ORCID,Suib Steven L.⁹¹⁰¹¹⁸^ORCID,Yang Tao¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Chongqing University

3. Chongqing 401331

4. People's Republic of China

5. Department of Chemistry and Chemical Engineering

6. University of Tennessee

7. Knoxville

8. USA

9. Department of Chemistry

10. University of Connecticut

11. Storrs

Abstract

t-BuOO* activated by Cr-PKU-8 from TBHP is the key intermediate to the highly selective dehydrogenation of sec-alcohols.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Chongqing

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01822H

Reference60 articles.

1. R. A. Sheldon and J. K.Kochi , Metal-catalyzed oxidations of organic compounds , New York , 1981

2. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?

3. New protocol of copper-catalyzed oxidative C(CO) C bond cleavage of aryl and aliphatic ketones to organic acids using O2 as the terminal oxidant

4. Iron and Copper Active Sites in Zeolites and Their Correlation to Metalloenzymes

5. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C–H Imidoylation of Heterocycle-Containing Molecules

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