An oxygen-passivated vanadium cluster [V@V10O15]− with metal–metal coordination produced by reacting Vn− with O2-Reference-Cited by-同舟云学术

An oxygen-passivated vanadium cluster [V@V10O15]− with metal–metal coordination produced by reacting Vn− with O2

Published:2021 Issue:2 Volume:23 Page:921-927
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhang Hanyu¹²³⁴⁵^ORCID,Cui Chaonan¹²³⁴⁵,Yan Miao⁶⁷⁸,Geng Lijun¹²³⁴⁵^ORCID,Wu Haiming¹²³⁴⁵,Jia Yuhan¹²³⁴⁵,Luo Zhixun¹²³⁴⁵^ORCID,Li Si-Dian⁶⁷⁸^ORCID

Affiliation:

1. Beijing National Laboratory of Molecular Sciences (BNLMS)

2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species

3. Institute of Chemistry

4. Chinese Academy of Sciences

5. Beijing 100190

6. Institute of Molecular Science

7. Taiyuan 030006

8. China

Abstract

An oxygen-passivated vanadium cluster [V@V₁₀O₁₅]⁻ is reported by reacting V_n⁻ with O₂, giving rise to superatom features of metal–metal coordination and 3D aromaticity.

Funder

National Natural Science Foundation of China

Key Research Program of Frontier Science, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05385F

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