Molecular precursor-mediated facile synthesis of photo-responsive stibnite Sb2S3 nanorods and tetrahedrite Cu12Sb4S13 nanocrystals

Author:

Thomas Agnes1,Karmakar Gourab23ORCID,Shah Alpa Y.2,Lokhande Saili Vikram1,Kulkarni Atharva Yeshwant1,Tyagi Adish23ORCID,Singh Chauhan Rohit1ORCID,Kumar N. Naveen4,Singh Avadhesh Pratap5

Affiliation:

1. Department of Chemistry, K. J. Somaiya College of Science and Commerce, Vidyavihar, Mumbai 400077, India

2. Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, Homi Bhabha National Institute, Mumbai 400094, India

3. Homi Bhabha National Institute, Anushaktinagar, Mumbai 400094, India

4. Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085, India

5. Department of Chemistry, Kamla Nehru Institute of Physical and Social Sciences, Sultanpur-228118, India

Abstract

A facile synthetic route to access phase pure Sb2S3 and Cu12Sb4S13 nanostructures from a new molecular precursor Sb(4,6-Me2pymS)3 has been established. These nanostructures demonstrate high photoresponsivity with fast switching characteristics.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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