Encapsulation of the vanadium substituted Keggin polyoxometalates [α-PVW11O40]4− and [α-PV2W10O40]5− in HKUST-1

Author:

Orozco José C.1,Shuaib Damola T.1,Swenson LaSalle1,Chen Ying-Pin2,Chen Yu-Sheng2,Khan M. Ishaque1ORCID

Affiliation:

1. Department of Chemistry, Illinois Institute of Technology, Chicago, IL 60616, USA

2. ChemMatCARS, The University of Chicago, Lemont, IL 60439, USA

Abstract

Solid state UV-vis reflectance spectra reveal the distinct electronic structure of POM@MOF materials obtained by synthetic encapsulation of mono- and di-vanadium substituted Keggin polyoxotungstates in HKUST-1.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Reference79 articles.

1. M. T.Pope , Heteropoly and Isopoly Oxometalates , Springer, Verlag , West Berlin , 1983

2. E.Papaconstantinou and A.Hiskia , in Polyoxometalate Molecular Science , ed. J. J. Borrás-Almenar , E. Coronado , A. Müller and M. Pope , Springer , Netherlands , 2003 , pp. 381–416

3. Electrochemistry of Polyoxometalates: From Fundamental Aspects to Applications

4. I. V.Kozhevnikov , Catalysis by Polyoxometalates: Catalysts for Fine Chemical Synthesis 2 , John Wiley & Sons , West Sussex, England , 2002

5. J. B.Moffat , Metal-Oxygen Clusters: The Surface and Catalytic Properties of Heteropoly Oxometalates , Kluwer Academic Publishers. , New York , 2001

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